No he's just not paying attention. The wanted quests are built into both the leveling guides and the "Zandalar Forever" achievement guide. They aren't in the rep guide because they are not repeatable and by the time you hit max level they should be done. You'll also notice the rep guide doesn't contain every single possible completable quest that rewards rep. It is designed to focus on repeatable objectives, world quests, large quest lines, and missions.
DoTs: Assuming that the mob is going to live for certain periods of time, it is worth it to place DoTs up. If the mob lives for at least five seconds, cast Pain. If it lives at least seven seconds, cast VT. The ideal time to cast DoTs is when it would be replacing Flay, but you can substitute Blast if the mob will live longer. Make sure to cast Bolt on cd though!